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From what I have read, Paul Kantner was the driving force behind the Jefferson Airplane/Starship. Obviously neither was a one-man show, but aside from his credits as co-founder of the band, he is also credited as the one who rescussitated the band following their height of fame years. Sure ... there were other equally important "Jefferson" members (wouldn't want to belittle any of them, but Grace Slick and Marty Balin probably come next in the list for both incarnations).
While there are a number of other bands that came out the mid 60s/Summer of Love era in and around San Fransisco, for psychedelia, two stand out in my personal preferences, and they couldn't be more different in approach. (I know, this is a gross simplification that leaves out the more than 100 other Bay Area bands from that time, but .. Sly, Santana, Creedence don't really fit the psychedelia filter). So ... more different. The Dead = laid-back, rambling, a tinge of country: Airplane= in-your-face, hard-edged, with a sharp message: "Tear down the walls, m***f***s ")
Was Kanter a great guitar player? (One of the Google questions you'll see if you go digging.) Aside from asking for your personal opinion, I'll give mine. Considering the state of guitars, guitar playing, rock music in the late 60's ... I would say "good, not great". Having never seen him live (where you can really get a sense of one's skills), he did a good job with what he needed to do. Not flamboyant, but consider the effect (that is what counts?) of the guitar (opening guitar) on the Volunteers song: Nothing incredible - except that it is just what the song - and the song's message - needs.